
Handbook of Homogeneous Hydrogenation, 3 Volume Set
by de Vries, Johannes G.; Elsevier, Cornelis J.Buy New
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Summary
Author Biography
Hans de Vries was born in Amsterdam, the Netherlands (1951). In 1979 he received his Ph.D from the University of Groningen, were he worked under the guidance of Richard M. Kellogg on chiral, bridged dihydropyridines as NADH-mimetics. After a postdoctoral stint at Brandeis University, Waltham, USA with Jim Hendrickson (total synthesis of Methoxatin or PQQ) from 79-81 he moved back to Europe. From 1982-1988 he worked as medicinal chemist for Sandoz, first in Vienna, afterwards in London. Being more interested in chemistry than drugs he moved back to the Netherlands, were he took up employment with DSM, a multinational specialty chemicals company. His current job is Principal Scientist Homogeneous Catalysis for Fine Chemicals. Since 1998 he has been appointed as part-time professor at the University of Groningen. In 2000 he was appointed visiting industrial professor at the Univeristy of Bristol. During 2005 he was a visiting professor at the Universit+¬ Louis Pasteur, Strasbourg. His research interests are in the area of asymmetric hydrogenation (MonoPhos), aromatic substitution ("homeopathic" palladium), hydroformylation, metathesis, combinations of enzymes with transition metal catalysis, HTS, combinatorial catalysis and process intensification. He is (co-)author of 20 patents and over 100 publications. He is married and has three children.
Table of Contents
Foreword | |
Preface | |
List of Contributors | |
Introduction: Organometallic Aspects and Mechanism of Homogeneous Hydrogenation | |
Rhodium (Luis A. Oro and Daniel Carmona) | |
Introduction | |
The Early Years (1939-1970) | |
The [RhH(CO)(PPh3)3] Catalyst | |
The [RhCl(PPh3)3] Complex and Related Catalysts | |
The Cationic[Rh(diene)(PR3)X]+ Catalysts | |
Enantioselective Rhodium Catalysts | |
Some Dinuclear Catalyst Precursors | |
Concluding Remark | |
Abbreviations | |
References | |
Iridium (Robert H. Crabtree) | |
Introduction | |
Historical Aspects | |
Organometallic Aspects | |
Catalysis | |
Acknowledgments | |
Abbreviations | |
References | |
Ruthenium and Osmium (Robert H. Morris) | |
Introduction | |
Ruthenium | |
Osmium | |
Acknowledgment | |
Abbreviations | |
References | |
Palladium and Platinum (Paolo Pelagatti) | |
Introduction | |
Palladium | |
Platinum | |
Abbreviations | |
References | |
Nickel (Elisabeth Bouwman) | |
Introduction | |
Coordination Chemistry and Organometallic Aspects of Nickel | |
Hydrogenation Catalysis | |
Concluding Remarks | |
Abbreviations | |
References | |
Hydrogenation with Early Transition Metal, Lanthanide and Actinide Complexes (Christophe Coperet) | |
Introduction | |
Mechanistic Considerations | |
Group IV Metal Hydrogenation Catalysts | |
Hydrogenation Catalysts Based on Group III, Lanthanide, and Actinide Complexes | |
Hydrogenation Catalysts Based on Groups V-VII Transition-Metal Complexes | |
Supported Early Transition-Metal Complexes as Heterogeneous Hydrogenation Catalysts | |
Conclusions.Acknowledgments | |
Abbreviations | |
References | |
Ionic Hydrogenations (R. Morris Bullock) | |
Introduction | |
Stoichiometric Ionic Hydrogenations | |
Catalytic Ionic Hydrogenation | |
Ruthenium Complexes Having an OH Proton Donor and a RuH as Hydride Donor | |
Catalytic Hydrogenation of Ketones by Strong Bases | |
Conclusion | |
Acknowledgments | |
Abbreviations | |
References | |
Homogeneous Hydrogenation by Defined Metal Clusters | |
Introduction | |
Hydrogenation of C=C Bonds | |
Hydrogenation of CC Bonds | |
Hydrogenation of Other Substrates | |
Concluding Remarks | |
Abbreviations | |
References | |
Homogeneous Hydrogenation: Colloids - Hydrogenation with Noble Metal Nanoparticles | |
Introduction | |
Concepts | |
Hydrogenation of Compounds with C=C Bonds | |
Hydrogenation of Compounds with CC Bonds | |
Arene Hydrogenation | |
Hydrogenation of Compounds with C=O Bonds | |
Enantioselective Hydrogenation | |
Conclusion.Abbreviations.References | |
Kinetics of Homogeneous Hydrogenations: Measurement and Interpretation | |
Introduction | |
The Basics of Michaelis-Menten Kinetics | |
Hydrogenation From a Kinetic Viewpoint | |
Abbreviations | |
References | |
Spectroscopic Methods in Homogeneous Hydrogenation | |
Nuclear Magnetic Resonance Spectroscopy in Homogeneous Hydrogenation Research | |
Introduction | |
NMR Methods | |
Outlook.Abbreviations | |
References | |
Parahydrogen-Induced Polarization: Applications to Detect Intermediates of Catalytic Hydrogenations | |
In-Situ Spectroscopy | |
Ortho- and Parahydrogen | |
Applications of PHIP-NMR Spectroscopy | |
Catalyst-Attached Products as | |
Table of Contents provided by Publisher. All Rights Reserved. |
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