
Organic Molecular Solids
by Schwoerer, Markus; Wolf, Hans ChristophBuy New
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Summary
Author Biography
Professor Hans Christoph Wolf studied physics, chemistry and biology in Freiburg and Tubingen, both Germany, where he received his Ph.D. in 1952. From 1952 to 1954, he held a post as a researcher in physical chemistry at the Technical University of Munich. After working for several years as an assistant professor, he was awarded a full professorship at the Third Physical Institute of the University of Stuttgart, of which he also became the director, and from which he retired in 1997. Professor Wolf received the Otto Hahn Award of the German Physical Society and the Society of German Chemists in 2000. He was a member of the editorial boards of numerous international journals and is one of the most renowned and established authors in the fields of atomic and quantum physics. His field of research is the physics of organic solids.
Table of Contents
Introduction | |
What are Organic Solids? | |
What are the Special Characteristics of Organic Solids? | |
Goals and Future Outlook | |
Problems for Chapter 1 | |
Literature | |
Forces and Structures | |
Forces | |
Inductive Forces | |
Van der Waals Forces | |
Repulsive Forces | |
Intermolecular Potentials | |
Coulomb Forces | |
Crystals of Nonpolar Molecules | |
Crystals of Molecules with Polar Substituents | |
Crystals with a Low Packing Density, Clathrates | |
Crystals of Molecules with Charge Transfer, Radical-ion Salts | |
Polymer Single Crystals: Diacetylenes | |
Thin Films | |
Inorganic-Organic Hybrid Crystals | |
Problems for Chapter 2 | |
Literature | |
Purification of Materials, Crystal Growth and Preparation of Thin Films | |
Purification | |
Highest Purity | |
Crystal Growth | |
Mixed Crystals | |
Epitaxy, Ultrathin Films | |
Problems for Chapter 3 | |
References | |
Impurities and Defects | |
Foreign Molecules, Impurities, and X traps | |
Structural Defects | |
Point Defects | |
Dislocations | |
Grain Boundaries | |
Dipolar Disorder | |
Characterisation and Analysis of Impurities | |
Characterisation of Defects | |
Literature | |
Introduction | |
Intramolecular Vibrations | |
Phonons | |
The Eigenvector | |
The Wavevector | |
The Frequencies (K) | |
Excitations | |
Experimental Methods | |
Inelastic Neutron Scattering | |
Raman Scattering and Infrared Absorption | |
The 12 External Phonons of the Naphthalene Crystal | |
Dispersion relations | |
Pressure and Temperature Dependencies | |
Analytic Formulation of the Lattice Dynamics in Molecular Crystals | |
Phonons in other Molecular Crystals | |
Hindered Rotation and Diffusion | |
Nuclear Magnetic Resonance | |
Benzene Crystals | |
Methyl Groups | |
Diffusion | |
Problems for Chapter 5 | |
References | |
Electronic Excited States, Excitons, Energy Transfer | |
Introduction | |
Some historical remarks | |
Optical Excited States in Crystals | |
Davydov Splitting and Mini-Excitons | |
Frenkel Excitons | |
Excitonic States, Fundamental Equations | |
Polarisation and Band Structure | |
Coherence | |
Charge Transfer (CT) Excitons | |
Surface Excitons | |
Excimers | |
Exciton Processes, Energy Conduction | |
Sensitised Fluorescence | |
Delayed Fluorescence by Triplet Excitons | |
Excitonic Processes | |
Excitonic Processes in other Systems | |
Future Developments | |
Problems for Chapter 6 | |
Literature | |
Structure and Dynamics of Triplet States | |
Introduction and Historical Remarks | |
Spin Quantisation in Triplet States | |
The Dipole-Dipole Interaction, Fine Structure | |
Zero Field (B0 = 0) | |
Zeeman Splitting (B0 = 0) | |
Powder Spectra | |
Mini-Excitons | |
& | |
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