
Terpyridine-based Materials For Catalytic, Optoelectronic and Life Science Applications
by Schubert, Ulrich S.; Winter, Andreas; Newkome, George R.Buy New
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Summary
Author Biography
Table of Contents
Preface | p. ix |
List of Abbreviations | p. xi |
Introduction | p. 1 |
Synthesis, Properties, and Applications of Functionalized 2,2':6',2"-Terpyridines | p. 13 |
Introduction | p. 13 |
Basic Synthetic Strategies | p. 13 |
Ring Assembly Methodologies | p. 14 |
Cross Coupling Procedures | p. 18 |
Synthesis and Properties of 2,2':6',2"-Terpyridine Derivatives | p. 19 |
4'-Substituted 2,2':6',2"-Terpyridinoxy Derivatives | p. 19 |
Miscellaneous 4'-Substituted 2,2':6',2"-Terpyridine Derivatives | p. 24 |
2,2':6',2"-Terpyridines Symmetrically Substituted on the Outer Pyridine Rings | p. 28 |
Ziessel Type 2,2':6',2"-Terpyridines | p. 31 |
Krohnke Type 2,2':6',2"-Terpyridines | p. 38 |
Miscellaneous Terpyridine-Analogous Compounds | p. 49 |
Rigid U and S Shaped Terpyridines | p. 49 |
Five Membered N-Heterocycles Replacing the Outer Pyridine Rings | p. 51 |
The Swedish Concept: Expanded Bite Angles in Tridentate Ligands | p. 53 |
Chemistry and Properties of Terpyridine Transition Metal | p. 65 |
Introduction | p. 65 |
Basic Synthetic Strategies and Characterization Tools | p. 66 |
Ru11 and Os11 Complexes | p. 73 |
Synthesis of Ru11 and Os11 Bis(terpyridine) Complexes | p. 73 |
Ru11 Ions and Terpyridine Ligands-A Happy Marriage? | p. 75 |
Photophysical Properties | p. 75 |
Mononuclear Ru Bis(terpyridine) Complexes | p. 76 |
Oligonuclear Complexes Containing Ru/Os11 Bis(terpyridine) Units | p. 89 |
Dendritic and Star-Shaped Systems Containing Ru11 Bis(terpyridine) Units | p. 102 |
Iridium (III) Complexes with Terpyridine Iigands | p. 107 |
Platinum(II) Mono(terpyridine) Complexes | p. 115 |
Metallo Supramolecular Architectures Based on Terpyridine Complexes | p. 129 |
Introduction | p. 129 |
Terpyridme Containing Metallo Macrocycles | p. 130 |
The HETTAP Concept | p. 148 |
Racks and Grids | p. 154 |
Helicates | p. 171 |
Rotaxanes and Catenanes | p. 177 |
Miscellaneous Structures | p. 182 |
Cyclodextrin Derivatives | p. 182 |
Other Assemblies | p. 185 |
¿-Conjugated Polymers Incorporating Terpyridine Metal Complexes | p. 199 |
Introduction | p. 199 |
Metallo Supramolecular Polymerization | p. 200 |
Metallopolymers Based on Conjugated Bis(terpyridine)s | p. 204 |
Polymerization by Transition Metal Ion Coordination | p. 204 |
Self Assembly of Metallopolymers | p. 212 |
Chiral Metallopolymers | p. 219 |
Non Classical Metallopolymers | p. 220 |
Polymerization Using the "Complex First" Method | p. 224 |
Main Chain Metallopolymers Based on Terpyridine Functionalized ¿-Conjugated Polymers | p. 229 |
Functional Polymers Incorporating Terpyridine-Metal Complexes | p. 242 |
Introduction | p. 242 |
Polymers with Terpyridine Units in the Side Chain | p. 242 |
Materials Based on Flexible Organic Polymers | p. 242 |
Materials Based on Conjugated Polymers | p. 257 |
Polymers with Terpyridines within the Polymer Backbone | p. 262 |
Polymers from Organic Small-Molecule Building Blocks | p. 263 |
Chain-Extended Polymers from Polymeric Building Blocks | p. 269 |
Monotopic Macroligands by End Group Funtionalization | p. 272 |
Functional Terpyridine Containing Initiators | p. 277 |
Initiation of Ionic Polymerization Reactions | p. 277 |
Initiation of Controlled Radical Polymerization Reactions | p. 281 |
Post Polymerization Functionalization | p. 288 |
Mononuclear Metallo-supramolecular Polymers | p. 291 |
Supramolecular A-[M]-A Homopolymers | p. 291 |
Supramolecular Block Copolymers | p. 294 |
Oligonuclear Metallo Supramolecular Copolymers | p. 308 |
Terpyridine Metal Complexes and their Biomedical Relevance | p. 319 |
Introduction | p. 319 |
Terpyridine Metal Complexes with Biological Activity | p. 320 |
Intercalation and Cytotoxicity | p. 320 |
Terpyridine Complexes with d8 Late Transition Metal Ions | p. 320 |
Terpyridine Complexes with Heavy d6 Transition Metal Ions | p. 350 |
Terpyridine Complexes with MisceEaneous Transition Metal Ions | p. 364 |
Biolabeling | p. 376 |
Terpyridines and Nanostructures | p. 399 |
Introduction | p. 399 |
Terpyridines and Surface Chemistry | p. 401 |
Terpyridines and Inorganic Nanomaterials | p. 420 |
Terpyridines and Nano Structured TiO2: Photovoltaic Applications | p. 431 |
Organopolymeric Resins, Beads, and Nanoparticles | p. 447 |
Catalytic Applications of Terpyridines and Their Transition Metal Complexes | p. 459 |
Introduction | p. 459 |
Asymmetric Catalysts in Organic Reactions | p. 460 |
Electrocatalytic Oxidation and Reduction Processes | p. 476 |
Photocatalytic Processes | p. 480 |
Light-Driven Hydrogen Formation | p. 483 |
Molecular Terpyridine Based Catalysts for Water Oxidation | p. 488 |
Concluding Remarks | p. 507 |
Index | p. 509 |
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