Terpyridine-based Materials For Catalytic, Optoelectronic and Life Science Applications

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Edition: 1st
Format: Hardcover
Pub. Date: 2011-11-07
Publisher(s): Wiley-VCH
List Price: $213.14

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Summary

The book examines and presents in detail the formation of terpyridine complexes through metal-ligand coordination. The most successful synthetic pathways are highlighted, followed by an in-depth discussion of the properties of the resulting molecular compounds. A major part of the book is devoted to terpyridine-based supramolecular architectures which are the basis for a variety of existing and emerging applications such as organic solar cells and transistors, conducting nanowires and molecular switches.

Author Biography

Ulrich S. Schubert performed his Ph.D. work under the supervision of Prof. C. D. Eisenbach (Bayreuth, Germany) and Prof. C. R. Newkome (Florida, USA). After a postdoctoral training with Prof.J.M. Lehn at the University Strasbourg (France), he moved to the Munich University of Technology (Germany) to obtain his habilitation in 1999. From 1999 to spring 2000, he held a temporary position as a professor at the Center for NanoScience at the LMU Munich. From June 2000 to March 2007, he was Full-Professor at the Eindhoven University of Technology (Chair for Macromolecular Chemistry and Nanoscience), the Netherlands. Since April 2007, he is Full Professor at the Friedrich-Schiller-University Jena (Chair of Organic and Macromolecular Chemistry), Germany. He has published over 500 papers, 18 patents, and edited/written 5 scientific books. Andreas Winter studied chemistry at the University of Dortmund (Germany), where he graduated in organic chemistry in 1999. In 2003, he received his Ph.D. in chemistry (University of Paderborn, Germany) for work on applications of the Mannich reaction in the synthesis of pyridine derivatives under supervision of Professor N. Risch, and stayed on as a postdoc. Subsequently, in 2005 he joined the group of Prof. U. S. Schubert (Eindhoven University of Technology, The Netherlands and Friedrich Schiller University Jena, Germany). His research is focused on the synthesis of emissive and luminescent metallo-supramolecular assemblies. George R. Newkome received his B.S. and Ph.D. in chemistry from Kent State University. He became a full professor in 7978 and Distinguished Research Master in 1982 at Louisiana State University, In 1986, he moved to the University of South Florida as Vice President for Research and Professor of Chemistry, becoming a Distinguished Research Professor in 1992. In 2001, he became Vice President for Research and Dean of the Graduate School at The University of Akron. He is the Oelschlager Professor of Science and Technology and professor in the departments of Polymer Science and Chemistry. Currently, he is the President and CEO of the University of Akron's Research Foundation and the Akron Innovation Campus. He has published over 430 papers, 45 patents, and edited/written over 15 scientific books and monographs.

Table of Contents

Prefacep. ix
List of Abbreviationsp. xi
Introductionp. 1
Synthesis, Properties, and Applications of Functionalized 2,2':6',2"-Terpyridinesp. 13
Introductionp. 13
Basic Synthetic Strategiesp. 13
Ring Assembly Methodologiesp. 14
Cross Coupling Proceduresp. 18
Synthesis and Properties of 2,2':6',2"-Terpyridine Derivativesp. 19
4'-Substituted 2,2':6',2"-Terpyridinoxy Derivativesp. 19
Miscellaneous 4'-Substituted 2,2':6',2"-Terpyridine Derivativesp. 24
2,2':6',2"-Terpyridines Symmetrically Substituted on the Outer Pyridine Ringsp. 28
Ziessel Type 2,2':6',2"-Terpyridinesp. 31
Krohnke Type 2,2':6',2"-Terpyridinesp. 38
Miscellaneous Terpyridine-Analogous Compoundsp. 49
Rigid U and S Shaped Terpyridinesp. 49
Five Membered N-Heterocycles Replacing the Outer Pyridine Ringsp. 51
The Swedish Concept: Expanded Bite Angles in Tridentate Ligandsp. 53
Chemistry and Properties of Terpyridine Transition Metalp. 65
Introductionp. 65
Basic Synthetic Strategies and Characterization Toolsp. 66
Ru11 and Os11 Complexesp. 73
Synthesis of Ru11 and Os11 Bis(terpyridine) Complexesp. 73
Ru11 Ions and Terpyridine Ligands-A Happy Marriage?p. 75
Photophysical Propertiesp. 75
Mononuclear Ru Bis(terpyridine) Complexesp. 76
Oligonuclear Complexes Containing Ru/Os11 Bis(terpyridine) Unitsp. 89
Dendritic and Star-Shaped Systems Containing Ru11 Bis(terpyridine) Unitsp. 102
Iridium (III) Complexes with Terpyridine Iigandsp. 107
Platinum(II) Mono(terpyridine) Complexesp. 115
Metallo Supramolecular Architectures Based on Terpyridine Complexesp. 129
Introductionp. 129
Terpyridme Containing Metallo Macrocyclesp. 130
The HETTAP Conceptp. 148
Racks and Gridsp. 154
Helicatesp. 171
Rotaxanes and Catenanesp. 177
Miscellaneous Structuresp. 182
Cyclodextrin Derivativesp. 182
Other Assembliesp. 185
¿-Conjugated Polymers Incorporating Terpyridine Metal Complexesp. 199
Introductionp. 199
Metallo Supramolecular Polymerizationp. 200
Metallopolymers Based on Conjugated Bis(terpyridine)sp. 204
Polymerization by Transition Metal Ion Coordinationp. 204
Self Assembly of Metallopolymersp. 212
Chiral Metallopolymersp. 219
Non Classical Metallopolymersp. 220
Polymerization Using the "Complex First" Methodp. 224
Main Chain Metallopolymers Based on Terpyridine Functionalized ¿-Conjugated Polymersp. 229
Functional Polymers Incorporating Terpyridine-Metal Complexesp. 242
Introductionp. 242
Polymers with Terpyridine Units in the Side Chainp. 242
Materials Based on Flexible Organic Polymersp. 242
Materials Based on Conjugated Polymersp. 257
Polymers with Terpyridines within the Polymer Backbonep. 262
Polymers from Organic Small-Molecule Building Blocksp. 263
Chain-Extended Polymers from Polymeric Building Blocksp. 269
Monotopic Macroligands by End Group Funtionalizationp. 272
Functional Terpyridine Containing Initiatorsp. 277
Initiation of Ionic Polymerization Reactionsp. 277
Initiation of Controlled Radical Polymerization Reactionsp. 281
Post Polymerization Functionalizationp. 288
Mononuclear Metallo-supramolecular Polymersp. 291
Supramolecular A-[M]-A Homopolymersp. 291
Supramolecular Block Copolymersp. 294
Oligonuclear Metallo Supramolecular Copolymersp. 308
Terpyridine Metal Complexes and their Biomedical Relevancep. 319
Introductionp. 319
Terpyridine Metal Complexes with Biological Activityp. 320
Intercalation and Cytotoxicityp. 320
Terpyridine Complexes with d8 Late Transition Metal Ionsp. 320
Terpyridine Complexes with Heavy d6 Transition Metal Ionsp. 350
Terpyridine Complexes with MisceEaneous Transition Metal Ionsp. 364
Biolabelingp. 376
Terpyridines and Nanostructuresp. 399
Introductionp. 399
Terpyridines and Surface Chemistryp. 401
Terpyridines and Inorganic Nanomaterialsp. 420
Terpyridines and Nano Structured TiO2: Photovoltaic Applicationsp. 431
Organopolymeric Resins, Beads, and Nanoparticlesp. 447
Catalytic Applications of Terpyridines and Their Transition Metal Complexesp. 459
Introductionp. 459
Asymmetric Catalysts in Organic Reactionsp. 460
Electrocatalytic Oxidation and Reduction Processesp. 476
Photocatalytic Processesp. 480
Light-Driven Hydrogen Formationp. 483
Molecular Terpyridine Based Catalysts for Water Oxidationp. 488
Concluding Remarksp. 507
Indexp. 509
Table of Contents provided by Ingram. All Rights Reserved.

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